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Marlex® 7104 Linear Low-Density Polyethylene (LLDPE)

Plastic mulch cover algricultural film

Marlex® 7104 LLDPE is designed for sheet extrusion where toughness, tear resistance and cap-layer adhesion matter. It supports coextruded cap layers on HDPE structures and is applicable to geomembranes such as landfill covers and flat or round-die products.

Leveraging decades of polyethylene manufacturing expertise, CPChem produces Marlex® LLDPE resins using advanced catalyst and process technologies designed to deliver consistent molecular architecture and dependable resin quality. This foundation enables sheet extrusion and thermoforming converters to achieve predictable processing behavior, uniform sheet thickness, and reliable mechanical performance across demanding LLDPE sheet applications. 

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Technical Specifications

Mechanical & Stress Crack Properties

PropertyTypical ValueTest Method
Density0.919 g/cm3ASTM D1505
Flow Rate (MI, 190°C/2.16 kg)0.35 g/10 minASTM D1238
Tensile Strength at Yield11 MPa (1,600 psi)ASTM D638
Elongation at Break700%ASTM D638
Flexural Modulus410 MPa (60,000 psi)ASTM D790
ESCR (Cond. B, 10% Igepal, F50)> 2,000 hASTM D1693
ESCR (Cond. C, 100% Igepal, F50)> 2,000 hASTM D1693
SP-NCTL> 1,000 hASTM D5397 (App.)

Thermal & Stability Properties

PropertyTypical ValueTest Method
Durometer Hardness (Shore D)51ASTM D2240
Vicat Softening Temperature100°C (212°F)ASTM D1525
Heat Deflection (66 psi, Method A)51°C (123°F)ASTM D648
Brittleness Temperature< -75°C (< -103°F)ASTM D746
Oxidative Induction Time (200°C)> 100 minASTM D3895

Nominal properties reported are typical of the product but do not reflect normal testing variance and therefore should not be used for specification purposes. Values are rounded. Physical properties were determined on compression molded specimens prepared in accordance with Procedure C of ASTM D4703, Annex A1.

Specifications: ASTM D4976 - PE 215  |  FDA 21 CFR 177.1520(c) 3.2a, use conditions B through H per 21 CFR 176.170(c)

Key Characteristics of Marlex® 7104 LLDPE  

Engineered for sheet extrusion and geomembrane applications, Marlex® 7104 LLDPE is a high-molecular-weight ethylene-hexene copolymer that delivers the stress crack resistance, melt strength, and processability that converters and geomembrane manufacturers require for demanding flat-die and large-format applications.  

Key characteristics include:

  • Outstanding ESCR: Resists environmental stress cracking under demanding service conditions, including long-term exposure in containment and barrier applications  
  • Good Melt Strength: Maintains stable extrusion behavior for consistent gauge control across heavy-gauge sheet and geomembrane production
  • Excellent Flexibility: Delivers the conformability and durability required for installed sheet and geomembrane applications across variable terrain and substrates
  • Good Processability: Runs reliably on flat-die and round-die extrusion equipment with predictable melt behavior and gauge consistency
  • Good Gloss: Produces sheet surfaces with the visual quality required for finished and coextruded sheet products
  • High Coefficient of Friction Values: Provides surface friction characteristics that support stable handling, stacking, and installation in containment applications

 

These LLDPE resin properties make Marlex® 7104 ideal for sheet extrusion and select geomembrane applications.  

LLDPE Resin for Sheet Extrusion and Geomembrane Applications

Depending on the grade, Marlex® LLDPE resins are used across flexible and semi-rigid processing methods. Marlex® 7104 LLDPE is optimized for sheet extrusion and geomembrane applications that require outstanding stress crack resistance, melt strength, and processability.

Sheet Extrusion

Non-exhaustive list of applications:

  • Coextruded cap layers on HDPE
  • Blends with HDPE

 

Geomembrane

Non-exhaustive list of applications:

  • Landfill covers
  • Flat and round-die products

 

These applications benefit from Marlex® 7104 LLDPE’s ability to deliver long-term stress crack resistance, consistent extrusion performance, and durable service life across demanding sheet and geomembrane installations.

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Why Choose CPChem as Your LLDPE Supplier

Hexene Copolymer Technology

Our hexene copolymer and gas-phase reactor technologies deliver the consistent molecular structure and stress crack resistance that demanding sheet and geomembrane applications require.

Dedicated Film & Sheet Technical Support

Our experienced technical teams partner with film and sheet extruders to support resin qualification, optimize processing, and troubleshoot demanding extrusion applications.

Broad LLDPE Portfolio

Our comprehensive range of Marlex® LLDPE resins supports diverse applications across film, coating, and sheet — with grades tailored to specific processing methods and end-use requirements.

ISO 9001-Certified Global Supply

Our ISO 9001-certified quality management systems and global manufacturing footprint provide the consistent resin performance and dependable supply that converters and specifiers depend on.

Commitment to Sustainability

Marlex® Anew™ Circular Polyethylene supports circular economy goals by enabling recycled content in demanding polyethylene applications.